2,4-Dichloro-N-(3-methylphenyl)benzenesulfonamide
نویسندگان
چکیده
In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformations of the N-C bonds in the C-SO(2)-NH-C segments have gauche torsions with respect to the S=O bonds. The dihedral angle between the two benzene rings is 68.6 (1)°. The crystal structure features inversion dimers linked by pairs of N-H⋯O hydrogen bonds.
منابع مشابه
2,4-Dichloro-N-(2-methylphenyl)benzenesulfonamide
In the title compound, C(13)H(11)Cl(2)NO(2)S, the methyl-substituted aromatic ring is disordered over two positions [occupancy ratio 0.705 (5):0.295 (5)]. The dihedral angles between the two aromatic rings are 74.9 (1) and 71.0 (3)° in the two disorder components. The crystal structure features centrosymmetric dimers linked by pairs of N-H⋯O hydrogen bonds.
متن کامل2,4-Dichloro-N-(4-methylphenyl)benzenesulfonamide
The title compound, C(13)H(11)Cl(2)NO(2)S, crystallizes with four independent mol-ecules in the asymmetric unit. In each of the four mol-ecules, the conformation of the N-C bond in the C-SO(2)-NH-C segment is gauche with respect to both S=O bonds. The mol-ecules are twisted at the S-N bonds with C-SO(2)-NH-C torsion angles of 60.6 (4), -59.7 (3), 63.9 (4) and 53.0 (4)°. The benzene rings in two...
متن کامل2,4-Dimethyl-N-(3-methylphenyl)benzenesulfonamide
In the structure of the title compound, C(15)H(17)NO(2)S, the dihedral angle between the two aromatic rings is 47.1 (1)°. In the crystal structure, mol-ecules are connected by N-H⋯O hydrogen bonds, forming C(4) chains running along the c axis.
متن کامل2,4-Dichloro-N-(3,4-dichlorophenyl)benzenesulfonamide
In the crystal structure of the title compound, C(12)H(7)Cl(4)NO(2)S, the conformation of the N-H bond is syn to the meta-chloro residue in the aniline benzene ring. The two aromatic rings are tilted relative to each other by 68.9 (1)°. N-H⋯O hydrogen bonds connect the mol-ecules into centrosymmetric dimers.
متن کامل2,4-Dichloro-N-(2,4-dimethylphenyl)benzenesulfonamide
In the title compound, C(14)H(13)Cl(2)NO(2)S, the C-SO(2)-NH-C torsion angle is -71.4 (4)°. The sulfonyl and aniline benzene rings are tilted relative to one another by 44.6 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010